Preparation and Characterization of Some Metal Complexes of the New Ligand : 2-[ 2-(5- Methyl benzothiazolyl )azo] -4-Methyl phenol ( 5-Me-BTAC ).

Main Article Content

R.T. Mehdi A. M. Ali

Abstract

 This work reports the synthesis and characterization of some Co(111), Ni(11), Cu(11), Zn(l 1), Cd(1 1) and Hg(11) chelates of the new benzothia-zolylazo Ligand ( 5-Me-BTAC ) . The compounds were Characterized by IR , electronic spectroscopy, magnetic susceptibility ,elemental analysis and molar conductance measurements . The elemental analysis suggest the formula [ ML2 ] x.nH2O where x=Cl , n=1 for M= Co(111) and x=o , n=o for the remaining metal ions Electronic spectra and magnetic susceptibility data has supported the proposed octahedral geometry of Co(111) Ni(11) and Cu(1 I) Complexes. Conductivity measurements refer to nonionic structure of these Complexes except of Co(111) .

Article Details

How to Cite
MEHDI, R.T.; ALI, A. M.. Preparation and Characterization of Some Metal Complexes of the New Ligand : 2-[ 2-(5- Methyl benzothiazolyl )azo] -4-Methyl phenol ( 5-Me-BTAC ).. Ibn AL- Haitham Journal For Pure and Applied Science, [S.l.], v. 18, n. 3, p. 50-58, june 2019. ISSN 2521-3407. Available at: <http://jih.uobaghdad.edu.iq/index.php/j/article/view/2222>. Date accessed: 16 sep. 2019.
Section
Chemistry