Synthesis and Spectroscopic of Some new Metal Ions Complexes's with [N-(4-Methoxy Benzoyl Amino)-Thioxo Methyl] Leucine

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Basima M. Sarhan
Hassan A. Hassan
Bushra M. Fayyadh

Abstract

 A new ligand [N-(4-methoxy benzoyl amino)-thioxo methyl ] leucine  (MBL) was prepared from the reaction of (4-methoxy benzoyl isothiocyanate with leucine acid in molar ratio (l:l), it was characterized by elemental analysis (C.H.N.S), FT-IR, UV-Vis, 1H and 13CNMR. The complexes of the bivalent ions (Mn, Fe, Co, Ni, Cu, Zn, Cd and Hg ) have been prepared and characterized too.       The structural was established by elemental analysis (C.H.N.S), FT-IR, UV-Vis spectra,  conductivity measurements atomic absorption and magnetic susceptibility and determination of molar ration (M:L). The complexes showed characteristic behavior of tetrahedral geometry around the metal ions except with (Cu) complex showed square planer.

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How to Cite
Synthesis and Spectroscopic of Some new Metal Ions Complexes’s with [N-(4-Methoxy Benzoyl Amino)-Thioxo Methyl] Leucine. (2017). Ibn AL-Haitham Journal For Pure and Applied Sciences, 26(3), 313-323. https://jih.uobaghdad.edu.iq/index.php/j/article/view/442
Section
Chemistry

How to Cite

Synthesis and Spectroscopic of Some new Metal Ions Complexes’s with [N-(4-Methoxy Benzoyl Amino)-Thioxo Methyl] Leucine. (2017). Ibn AL-Haitham Journal For Pure and Applied Sciences, 26(3), 313-323. https://jih.uobaghdad.edu.iq/index.php/j/article/view/442