Theory and Calculation of the Reorganization Energy of Electron Transfer at Liquid/Liquid Interface

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Hadi Jabbar Al-Agealy Adil Ali Al-Saadi

Abstract

A description of the theoretical of the reorganization energies have been described  according to the outer-sphere Marcus model .It  is a given expression according this model unable to evaluate the reorganization energy for electron transfer at liquid /liquid interface. The spherical model approach have been used to  evaluate the radius of donor and acceptor liquid alternatively .Theoretical results of  the reorganization free energy for electron transfer at liquid/liquid interface system was  carried out . Matlap program is then used to calculate 𝐸0 for electron transfer reaction between water donor stated and many liquid acceptor state. This shows a good  agreement with the experiment. The results calculation shows that 𝐸0 is a function of dielectric constant  and refractive index and polarity of acceptor

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How to Cite
AL-AGEALY, Hadi Jabbar; AL-SAADI, Adil Ali. Theory and Calculation of the Reorganization Energy of Electron Transfer at Liquid/Liquid Interface. Ibn AL- Haitham Journal For Pure and Applied Science, [S.l.], v. 26, n. 2, p. 104-111, apr. 2017. ISSN 2521-3407. Available at: <http://jih.uobaghdad.edu.iq/index.php/j/article/view/489>. Date accessed: 13 oct. 2019.
Section
physics