Synthesis, Spectroscopic and Biological Studies of a New Some Complexes with N-Pyridin-2-Ylmethyl-Benzene-1,2Diamine

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Shaymaa H. Naji
Lekaa K. Abdul Karim
Falih H. Mousa

Abstract

 N-Pyridin-2-ylmethyl-benzene-1,2-diamine (L) was prepared from the reaction of ortho amino phenyl thiol with 2 – amino methyl pyridine in mole ratio (1:1) . It was characterized by elemental analysis (C.H.N) , FT-IR , Uv – Vis , 1H , 13C-N.M.R . The complexes of the bivalent ions (Co , Ni , Cu ,Pd , Cd , Hg and Pb) and the trivalent (Cr) have been prepared and characterized too . The structural was established by elemental analysis (C.H.N) , FT-IR , Uv – Vis spectra , conductivity measurements , atomic absorption and magnetic susceptibility . The complexes showed characteristic behavior of octahedral geometry around the metal ions and the (N,N,N) ligand coordinated in tridentat mode except with Pd complexes showed sequare planer . α ,Kf,εmax for the complexes were estimated too. β for Co – complex was calculated . The study of biological activity of the ligand (L) and its complexes showed various activity toward staphylococcus aureus and E.coli.  

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How to Cite
Synthesis, Spectroscopic and Biological Studies of a New Some Complexes with N-Pyridin-2-Ylmethyl-Benzene-1,2Diamine. (2017). Ibn AL-Haitham Journal For Pure and Applied Sciences, 26(1), 193-207. https://jih.uobaghdad.edu.iq/index.php/j/article/view/525
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Chemistry

How to Cite

Synthesis, Spectroscopic and Biological Studies of a New Some Complexes with N-Pyridin-2-Ylmethyl-Benzene-1,2Diamine. (2017). Ibn AL-Haitham Journal For Pure and Applied Sciences, 26(1), 193-207. https://jih.uobaghdad.edu.iq/index.php/j/article/view/525