Adenine as Environmentally- Friendly Corrosion Inhibitor for Stainless Steel in Sodium Chloride Acid Solution

Authors

  • Wisal A. Isa
  • Marwa S. Hussain

Keywords:

Stainless steel; Adenine, Tafel polarization, kinetic parameters, Thermodynamic parameters.

Abstract

The corrosion behavior and the influence of the concentration of adenine (AD) on the corrosion of 316L stainless steel in 0.6 mol.dm-3 sodium chloride acid solutions were studied. The research was performed in two pH values (pH=2 and pH=4) over the temperature range (293- 308)K. The investigation involved electrochemical polarization method using potentiostatic technique. Tafel polarization study revealed that (AD) acted as a mixed inhibitor. The inhibition efficiency increased with an increase in the concentration of adenine, but decreased with increase in temperature. (efficiency= 87% at 0.01 M AD & at T= 293K). The adsorption of (AD) has been found to occur on the surface of 316L stainless steel according to the Langmuir isotherm. The kinetic and thermodynamic parameters for stainless corrosion and adenine adsorption respectively were determined and discussed.

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Published

16-Mar-2017

Issue

Section

Chemistry

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