Oxidizing Gas Sensing Using SnO2 Thin Film Prepared by Thermal Evaporation Method

Authors

DOI:

https://doi.org/10.30526/39.2.4294

Keywords:

SnOx, Thin films, X-ray diffraction (XRD), Surface roughness, Gas sensor

Abstract

A SnOx thin film with a thickness of 400 ± 20 nm was deposited on a glass substrate and thermally oxidized at temperatures ranging from 573 K to 673 K. The structural surface morphology of SnOx thin films is checked. X-ray diffraction analysis indicated that films oxidized at 573K and 623K contain SnO, Sn3O4, and SnO2, as well as residual metallic tin. When the oxidation temperature was increased to 673K, the SnO₂ peaks became more prominent while the metallic Sn peak weakened. AFM studies indicated that the roughness of the films changed with different oxidation temperatures, which means that the oxidation temperature has a direct effect on the surface nature of the SnOx films. On the other hand, films oxidized at 673K (SnO2) are useful in gas sensor applications. The sensitivity (S) of the sensors manufactured for Oxidizing Gas (NO₂) was measured at room temperature and 373 and 473 K.  The maximum sensitivity appeared for the sample at a 373 K operating temperature, which is 7.33%. The sample exhibited the lowest response time at an operating temperature of 473 K.

Author Biographies

  • Zinah Abdulateef Abbas, Department of physics, College of Education for Pure Science / Ibn Al-Haitham, University of Baghdad, Baghdad, Iraq

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  • Seham Hassan Salman, Department of physics, College of Education for Pure Science / Ibn Al-Haitham, University of Baghdad, Baghdad, Iraq

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References

1. Jayaprakash RN, Mariappan R. Effect of substrate temperature on the structural, optical and electrical properties of tin oxide thin films. Chalcogenide Lett. 2021;18(4):191–200. https://doi.org/10.15251/CL.2021

2. McCluskey MD, Janotti A. Defects in semiconductors. J Appl Phys. 2020;127:190401. https://doi.org/10.1063/5.0012677

3. Ling YL, Zhi ML, Hong TC, Zheng Y, Yuan YS, Ai HC. Phase and optical characterizations of annealed SnO thin films and their p-type TFT application. J Electrochem Soc. 2010;157(6):H598–H602. https://doi.org/10.1149/1.3385390

4. Comini E, Faglia G, Sberveglieri G. UV light activation of tin oxide thin films for NO₂ sensing at low temperatures. Sens Actuators B Chem. 2001;78(1–3):73–77. https://doi.org/10.1016/S0925-4005(01)00796-1

5. Dey A. Semiconductor metal oxide gas sensors: A review. Mater Sci Eng B. 2018;229:206–217. https://doi.org/10.1016/j.mseb.2017.12.036

6. Jiangyang LC, Wang QY, Yuan GXZ, Xishuang L, Peng SGL. Hydrothermal synthesis and gas sensing properties of flower-like Sn₃O₄. Sens Actuators B Chem. 2016;224:128–133. https://doi.org/10.1016/j.snb.2015.09.089

7. Wu G, Li F, Yu Z, Kong Z, Li YL, Zhi ML. Microstructure, optical and electrical properties of p-type SnO thin films. J Phys Conf Ser. 2021;1963:012003. https://doi.org/10.1088/1742-6596/1963/1/012003

8. Younus IA, Ezzat AM, Uonis MM. Preparation of ZnTe thin films using chemical bath deposition technique. Nanocomposites. 2020;6(4):165–172. https://doi.org/10.1080/20550324.2020.1865712

9. Shihui Y, Weifeng Z, Lingxia L, Dan X, Helei D, Yuxin J. Fabrication of p-type SnO₂ films via pulsed laser deposition using Sb dopant. Appl Surf Sci. 2013;286:417–420. https://doi.org/10.1016/j.apsusc.2013.09.107

10. Chalise R, Thakur PK, Nakarmi JJ, Shrestha SP. Preparation of SnO₂ thin films by spray pyrolysis and gas sensing application. J Nepal Phys Soc. 2021;7(2):144–150. https://doi.org/10.3126/jnphyssoc.v7i2.38635

11. Khalef WK, Hamza EK, Salman AA. Morphology, optical and electrical properties of SnO₂ thin films prepared by spray pyrolysis. Eng Tech J. 2015;33(3B). https://doi.org/10.30684/etj.33.3B.13

12. Hien VX, Lee JH, Kim JJ, Heo YW. Structure and NH₃ sensing properties of SnO thin films deposited by RF magnetron sputtering. Sens Actuators B Chem. 2014;194:134–141. https://doi.org/10.1016/j.snb.2013.12.086

13. Sun YL, Nabatame T, Chung JW, Sawada T, Miura H, Miyamoto M, Wenger C, Fischer I A. Compositional changes between metastable SnO and stable SnO₂ in sputtered films for p-type TFTs. Thin Solid Films. 2024;807:140548. https://doi.org/10.1016/j.tsf.2024.140548

14. Nwanna EC, Imoisili PE, Jen TC. Synthesis and characterization of SnO₂ thin films using metalorganic precursors. J King Saud Univ Sci. 2022;34:102123. https://doi.org/10.1016/j.jksus.2022.102123

15. Mustafa MH, Ali HM, Habubi NF, Hussein BH. Influence of annealing on optoelectronic properties of sprayed p-NiO/n-CdS. J Mater Sci Mater Electron. 2024;35(22). https://doi.org/10.1007/s10854-024-13259-z

16. Alsulami A, Alsalme A. Enhancement of structural, optical and optoelectrical properties of Sr-doped SnO₂ thin films. Physica B. 2025;699:416783. https://doi.org/10.1016/j.physb.2024.416783

17. Rodríguez-López J, Rangel R, Lara-Romero J, Quintana-Owen P, Bartolo-Pérez P, Ramos-Carrazco A. Structural parameters of ALD-SnO₂ thin films on Si substrates. J Ovonic Res. 2024;20(5):627–632. https://doi.org/10.15251/jor.2024.205.627

18. Verma A, Shriram K, Das B. Structural and optical characteristics of SnO₂ thin films grown at different substrate temperatures. J Optoelectron Biomed Mater. 2025;17(3):141–149. https://doi.org/10.15251/jobm.2025.173.141

19. Athab RH, Hussein BH. Fabrication and investigation of ZnTe thin films. Chalcogenide Lett. 2023;20(7):477–485. https://doi.org/10.15251/CL.2023.207.477

20. Khudayer IH, Hussein BH, Mustafa MH, Ibrahim AJ. Structural, optical and electrical properties of AgInSe₂ thin films. Ibn Al-Haitham J Pure Appl Sci. 2018;31(1). https://doi.org/10.30526/31.1.188

21. Hsieh JC, Liu CJ, Ju YH. Response characteristics of lead phthalocyanine gas sensor. Thin Solid Films. 1998;322:98–103. https://doi.org/10.1016/S0040-6090(97)00964-4

22. Kumar R, Mamta, Kumari R, Singh VN. SnO₂-based NO₂ gas sensor with outstanding sensing performance at room temperature. Micromachines. 2023;14(4):728. https://doi.org/10.3390/mi14040728

23. Najeeb JM, Mohammed Monawer E. Synthesis and characterization of NiO–CoO nanocomposite as CO₂ gas sensor. Samarra J Pure Appl Sci. 2025;7(2):170–184. https://doi.org/10.54153/sjpas.2025.v7i2.962

24. Hamdan AS, Ali IM. Enhancement of hydrothermal Co₃O₄ thin films as H₂S gas sensor by yttrium loading. Baghdad Sci J. 2019;16(1 Suppl). https://doi.org/10.21123/bsj.2019.16.1(suppl).0221

25. Zarrinkhameh M, Zendehnam A, Hosseini SM, Robatmili N, Arabzadegan M. Effect of oxidation and annealing temperature on SnO₂ properties. Bull Mater Sci. 2014;37(3):533–539. https://doi.org/10.1007/s12034-014-0702-1

26. Jamil SSB, Hateef AA, Atty HK. Physical properties of In₂O₃ thin films as CO₂ and H₂ gas sensors. Phys Sci Res Int. 2015;3(2):18–25. (no DOI available)

27. Chen W, Zhou Q, Wan F, Gao T. Gas sensing properties of nano-SnO₂ for hydrogen and carbon monoxide. J Nanomater. 2012;2012:612420. https://doi.org/10.1155/2012/612420

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Published

20-Apr-2026

Issue

Section

Physics

How to Cite

[1]
Abbas, Z.A. and Salman, S.H. 2026. Oxidizing Gas Sensing Using SnO2 Thin Film Prepared by Thermal Evaporation Method. Ibn AL-Haitham Journal For Pure and Applied Sciences. 39, 2 (Apr. 2026), 118–125. DOI:https://doi.org/10.30526/39.2.4294.