Synthesis and Characterization of Some Mixed-Ligand Complexes Containing Azo Dye and 1,10-phenanthroline with CoII, ZnII, CdII and HgII Ions

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Hasan A. Hasan
Wasan M. Alwan
Riyadh M. Ahmed
Enaam I.Yousif

Abstract

 In this work, the ligand was obtained from the reaction of diazonium salt of naphthyl amine with 1-amino-2-naphtol-4-sulfonic acid. The bidentate ligand  type (NO) donar atoms was reacted with 1,10-phenanthroline and matel salt in a 1:1:1 mole ratio to give the complexes, using NaOH as a base. Physical-chemical teqnichas were used to characteriz the prepared compounds FT-IR,U.V-Vis, fluorescence and 1HNMR spectroscopy, atomic absorption , chloride content along with conductivity and melting point measurements .Finally, thermal analysis was used to confirm the presence of coordination H2O molecule in the complexes structure. According to memtioned characterization methods, the general formula proposed for CoII ZnII, CdII and HgII complexes is [M(L)(phen)(H2O)Cl]. 

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How to Cite
A. Hasan, H., M. Alwan, W., M. Ahmed, R., & I.Yousif, E. (2017). Synthesis and Characterization of Some Mixed-Ligand Complexes Containing Azo Dye and 1,10-phenanthroline with CoII, ZnII, CdII and HgII Ions. Ibn AL- Haitham Journal For Pure and Applied Sciences, 28(3), 187–203. Retrieved from https://jih.uobaghdad.edu.iq/index.php/j/article/view/152
Section
Chemistry