Coordination Behavior of N2o Donor Ligand with Some Metalsions

Authors

  • Ali M. A. Al-khazraji

Keywords:

Schiff base, tridentate, Metal complexesand3-amino benzoic acid

Abstract

Tridentate Schiff base ligand L2 and its complexes with nickel(II), cobalt (II), copper (II), manganese (II) and mercury (II) ions have been synthesized by the condensation of 4Aminoantipyrine, Benzoin, then the ligand (L1) and 3-amino benzoic acid. The ligand and its complexes were described by 1H-&13C-NMR, UV-visible, FT-IR, (only ligand), molar conductance elemental, analysis and magnetic susceptibility, calculations. It has been set that the ligand acts as (N, N, O) neutral tridentate forming chelates with stoichimetry (metal: ligand) (1:1). all metal complexes is suggested Octahedral configuration. Most of the prepared compounds show antibacterial activity to (Staphylococcus aureus),(Escherichia coli), (Bacillussubtilis) and (Pseudomonas aeroginosa).

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Published

20-Feb-2017

Issue

Section

Chemistry

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