Using the Size Strain Plot Method to Specity Lattice Parameters

Authors

Marwah T. Jalil Department of Phesics,College of Education for Pure Sciences, Ibn Al - Haitham, University of Baghdad, Baghdad, Iraq
Khalid H. Harbbi Department of Phesics,College of Education for Pure Sciences, Ibn Al - Haitham, University of Baghdad, Baghdad, Iraq.

DOI:

https://doi.org/10.30526/36.1.2891

Keywords:

Department of Phesics,College of Education for Pure Sciences, Ibn Al - Haitham, University of Baghdad, Baghdad, Iraq

Abstract

X-ray diffractometers deliver the best quality diffraction data while being easy to use and adaptable to various applications. When X-ray photons strike electrons in materials, the incident photons scatter in a direction different from the incident beam; if the scattered beams do not change in wavelength, this is known as elastic scattering, which causes amplitude and intensity diffraction, leading to constructive interference. When the incident beam gives some of its energy to the electrons, the scattered beam's wavelength differs from the incident beam's wavelength, causing inelastic scattering, which leads to destructive interference and zero-intensity diffraction. In this study, The modified size-strain plot method was used to examine the pattern of x-ray diffraction lines (101),(121),(202),(042), and (242) for calcium titanate(CaTiO3) nanoparticles in this study. To calculate the new variables, the size strain plot method was created., X-ray line analysis and calculation of crystal size and lattice tension of calcium titanate oxide nanoparticles. It is used to calculate the crystal volume (44.7 nm) and to calculate the determination of network parameters such as the texture modulus (Tc), macro stress (MS), specific surface area (SSA), and dislocation density(η), respectively.

References

Bykkam, S.; Ahmadipour, M.; Narisngam, S.; Kalagadda, V. R.; Chidurala, S. C. Extensive studies on X-ray diffraction of green synthesized silver nanoparticles. Adv. Nanopart, 2015, 4, 1,1-10.‏

Holder, C. F.; Schaak, R. E.; Tutorial on powder X-ray diffraction for characterizing nanoscale materials. Acs Nano, 2019,13, 7, 7359-7365.‏

Shukla, P.; Subhasisa N.; Guanjun W.; Xiaojun S.; and Jonathan L.; Surface property modifications of silicon carbide ceramic following laser shock peening. Journal of the European Ceramic Society, 2017,37,9, 3027-3038,.

Gralik, G.; Raupp-Pereira, F.; Hotza, D.; Labrincha, J. A.; Zanelli, C.; Dondi, M.; Formation and quantification of calcium titanate with the perovskite structure from alternative sources of titanium.‏ Congresso Brasileiro de Engenharia e Ciência dos Materiais ,2014,503-510.

Langford, J. I.; Wilson, A. J.; Scherrer after sixty years: a survey and some new results in the determination of crystallite size. Journal of applied crystallography, 1978, 11, 2,102-113.‏

Sibum, H.; Güther, V.; Roidl, O.; Habashi, F.; Wolf, H. U.; Titanium, titanium alloys, and titanium compounds. Ullmann's encyclopedia of industrial chemistry.‏2000.

Cherdchom, S.; Rattanaphan, T.; Chanadee, T.; Calcium titanate from food waste: combustion synthesis, sintering, characterization, and properties. Advances in Materials Science and Engineering, 2019.‏ ID 9639016 | https://doi.org/10.1155/2019/9639016.

Monshi, A.; Foroughi, M.R.; Monshi, M.R.; Modified Scherrer Equation to Estimate More Accurately Nano-Crystallite Size Using XRD. World J. Nano Sci. Eng.2012, 2,154–160.

Anand, S.;Amaliya, A. P.; Janifer, M. A.; Pauline, S.; Structural, morphological and dielectric studies of zirconium substituted CoFe2O4 nanoparticles. Modern Electronic Materials, 2017, 3. 4,168-173.‏

Stylianou, R.; Tkadletz, M.; Schalk, N.; Penoy, M.; Czettl, C.; Mitterer, C.; Effects of reference materials on texture coefficients determined for a CVD α-Al2O3 coating. Surface and Coatings Technology, 2019, 359, 314-322.‏

Theivasanthi, T.; Alagar, M.; Titanium dioxide (TiO2) nanoparticles XRD analyses: an insight. arXiv preprint arXiv. 2013, 1307, 1091-2001.‏

Theivasanthi, T.; Alagar, M.; Chemical capping synthesis of nickel oxide nanoparticles and their characterizations studies. arXiv preprint arXiv. 2012, 1212, 4595.‏

Gao, Q. L.; Zhang, Y. L.; Zhou, J. M.; Peng, J. G.; Hu, S. L.; X-Ray Diffraction Characteristics of Kovar Alloy and Al2O3 Ceramics. Trans Tech Publications Ltd Materials Science Forum. 2016, 872, 123-127.‏

Badawi, E. A.; Abdel-Rahman, M. A.; Mostafa, A.; Abdel-Rahman, M.; Determination of the crystallite size and micro-strain by novel method from XRD profile. 2019. Appl. Phys, 2, 1-10

Raj, A. M. E.; Nehru, L.C.; Jayachandran, M.; Sanjeeviraja, C.; Spray pyrolysis deposition and characterization of highly (100) oriented magnesium oxide thin films. Cryst.Res.Technol. 2007,42. 867.