Processing Eruca sativa leaves in the nanoscale and study its effectiveness for removing Cibacron red dye from their aqueous solutions
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Abstract
The discharge of dyes into the water is a significant source of pollution, which is especially concerning given that textile mills are the primary contributor. Nanomaterial-based solutions to this issue have required extensive research and investigation due to their complex nature. In this research, novel nanoparticle were successfully synthesized using the leaves of the Eruca sativa plant. The nano was analyzed using scanning and transmission electron microscopy (SEM and TEM) measurements, and their crystal structure was determined using the X-ray diffraction technique (XRD). The incorporation of NPs resulted in an increase in the uptake of the Cibacron red dye. At a contact time of 30 minutes, observed a faster adsorption onto ES. In the process of describing the adsorption process, the Langmuir model (R2 =0.9817) and the pseudo-second-order model (R2 = 0.9884) were the most appropriate models to use. An investigation into thermodynamics was carried out in order to arrive at the following values for the parameters of G, H, and S: -1.173 kJ/mol, 16.794 J/mol K and 56.05 J/mol. In conclusion, the novel nano that was synthesized is an excellent adsorbate surface for the Cibacron- red dye.
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Tang H, Wang J, Yu S. Recent advances in nanoscale zero-valent iron-based materials: Characteristics, environmental remediation and challenges. J Clean Prod, 2021,319,128641.
Al-Kindi SG, Brook RD, Biswal S. Environmental determinants of cardiovascular disease: lessons learned from air pollution. Nat Rev Cardiol, 2020,17(10),656–72.
Shao S, Liu L, Tian Z. Does the environmental inequality matter? A literature review. Environ Geochem Health,2021,1–24.
Immerzeel WW, Davies BJ, Elmore AC. Importance and vulnerability of the world’s water towers. Nature, 2020,577(7790),364–9.
Mikhno I, Koval V, Garmatiuk O. Green economy in sustainable development and improvement of resource efficiency. Cent Eur Bus Rev, 2021,10(1),99–113.
Ponomarev A V, Ershov BG. The green method in water management: electron beam treatment. Environ Sci & Technol,2020,54(9),5331–44.
Farhan AM, Zaghair AM, Abdullah HI. Adsorption Study of Rhodamine –B Dye on Plant (Citrus Leaves). Baghdad Sci J, 2022,19(4),838–47.
Magureanu M, Bradu C, Hong D. A review on non-thermal plasma treatment of water contaminated with antibiotics. J Hazard Mater, 2021,417,125481.
Bhatt P, Mishra S, Chen S. New insights into the degradation of synthetic pollutants in contaminated environments. Chemosphere, 2021,268,128827.
Yoshikawa H, Wuermli AJ, Stein A. Effects of the global coronavirus disease-2019 pandemic on early childhood development: Short-and long-term risks and mitigating program and policy actions. J Pediatr, 2020,223,188–93.
Kadhim NJ, Mousa SA, Farhan AM, Muhammed EA. A comparative study of the adsorption of crystal violet dye from aqueous solution on rice husk and charcoal. Baghdad Sci J, 2020,17(1),295–304.
Okoro HK, Pandey S, Adeniyi AG. Nanomaterial-based biosorbents: Adsorbent for efficient removal of selected organic pollutants from industrial wastewater. Emerg Contam, 2022,8,46–58.
Vannini C, Domingo G, Onelli E. Morphological and proteomic responses of Eruca sativa exposed to silver nanoparticles or silver nitrate. PLoS One. 2013,8(7),e68752.
Organization WH. Global progress report on water, sanitation and hygiene in health care facilities: Fundamentals first, 2020.
Sridhar A, Ponnuchamy M, Prabhakar S. Valorization of food waste as adsorbents for toxic dye removal from contaminated waters: A review. J Hazard Mater, 2022,424,127432.
Kipçak .Ilker, Kurtaran Ersal E. Catalytic wet peroxide oxidation of a real textile azo dye Cibacron Red P-4B over Al/Fe pillared bentonite catalysts: Kinetic and thermodynamic studies. React Kinet Mech Catal,2021,132(2),1003–23.
Ahmed SF, Ong HC, Chia WY. Recent developments in physical, biological, chemical, and hybrid treatment techniques for removing emerging contaminants from wastewater. J Hazard Mater, 2021,416,125912.
Maity S, Sinha D, Sarkar A. Wastewater and industrial effluent treatment by using nanotechnology. In: Nanomaterials and Environmental Biotechnology. Springer, 2020, 299–313.
Kamil AF, Abdullah HI, Rheima AM, Mohammed SH. Cibacron red dye removal in aqueous solution using Synthesized CuNiFe2O5 Nanocomposite: Thermodynamic and kinetic studies. Egypt J Chem, 2021,64(11),6133–45.
Aboud NAA, Jasim BE, Rheima AM. Methylene orange dye removal in aqueous solution using synthesized cdo-mno2 nanocomposite: Kinetic and thermodynamic studies. Chalcogenide Lett, 2021,18(5),237–43.
Aboud NAA, Jasim BE, Rheima AM. Adsorption study of phosphate ions pollution in aqueous solutions using microwave synthesized magnesium oxide nanoparticles, 2021,16(3),801–7.
Vorokh AS. Scherrer formula: estimation of error in determining small nanoparticle size. Nanosyst Physics, Chem Math,2018,9(3),364–9.
Fuentes E, Carrasco G, Palomo I. A novel role of Eruca sativa Mill.(rocket) extract: Antiplatelet (NF-$κ$B inhibition) and antithrombotic activities. Nutrients, 2014,6(12),5839–52.
Alaraidh IA, Ibrahim MM, El-Gaaly GA. Evaluation of green synthesis of Ag nanoparticles using Eruca sativa and Spinacia oleracea leaf extracts and their antimicrobial activity. Iran J Biotechnol, 2014,12(1),50–5.
Said KAM, Baini R, Zauzi NSA. Application of freundlich and Temkin isotherm to study the removal of Pb(II) via adsorption on activated carbon equipped polysulfone membrane. Int J Eng Technol, 2018,7(3.18 Special Issue 18),91–3.
Revellame ED, Hernandez R, Zappi ME. Adsorption kinetic modeling using pseudo-first order and pseudo-second order rate laws: A review. Clean Eng Technol, 2020,1(December),100032.
Vadi M, Mansoorabad AO. Investigation of langmuir, freundlich and temkin adsorption isotherm of tramadol by multi-wall carbon nanotube. Asian J Chem, 2013,25(10),5467–9.