Impacts of Non-Thermal Plasma on the Structural and Optical Characteristics of Cr:Se Core-Shell Thin Films Synthesized Using Chemical Spray Pyrolysis

Authors

DOI:

https://doi.org/10.30526/38.3.4026

Keywords:

Cr:Se, Core-shell, Plasma jets, DBD, Thin film

Abstract

Over the past few years, there has been a significant focus on studying the synthesis and applications of metal nanoparticles. These tiny particles possess distinct properties that set them apart from bulk metals. Cr:Se core-shell nano thin film has been pre-coated by plasma jets with different concentrations (10:0, 8:2, and 6:4) and deposition by chemical spray pyrolysis. The nano-thin films were analyzed by X-ray diffraction (XRD), ultraviolet-visible spectroscopy(UV), and transmission electron microscopy TEM. This study looks into the structure and optical features of core-shell nanoparticles made with different ratios of chromium and selenium (Cr:Se). The X-ray diffraction patterns confirm the crystalline nature of the nanoparticles and the ratio (6:4). Exposing the best crystalline phase to non-thermal plasma (DBD) results in significant changes in the XRD, transitioning towards a more crystalline phase. Tauc plots show a non-linear trend in direct bandgap energies, meaning the energy gap increased (2.77-3.88 eV), notably increasing. Transmission electron microscopy analysis highlights improved nanoparticle distribution and uniformity. non-thermal plasma ( DBD ) significantly enhances the humidity sensitivity, thereby optimizing the nanoparticles for sensor applications. These findings underscore the potential of Cr:Se nanoparticles for advanced optoelectronic and sensing technologies and various technological applications. 

Author Biographies

  • Taghreed A. Hilmi, Department of Physics, College of Science for Women, University of Baghdad, Baghdad, Iraq.

    Department of Physics, College of Science for Women, University of Baghdad, Baghdad, Iraq.

  • Ramiz A. Al-Ansari, Department of Physics, College of Science for Women, University of Baghdad, Baghdad, Iraq.

    Department of Physics, College of Science for Women, University of Baghdad, Baghdad, Iraq.

References

1. Ghosh Chaudhuri R, Paria S. Core/shell nanoparticles: classes, properties, synthesis mechanisms, characterization, and applications. Chem Rev. 2012;112(4):2373–2433. https://doi.org/10.1021/cr100449n

2. Habibullah GJ, Viktorova T. Current strategies for noble metal nanoparticle synthesis. Nanoscale Res Lett. 2021;16(1):47. https://doi.org/10.1186/s11671-021-03480-8

3. Nguyen LN. Structural and optical sensing properties of nonthermal atmospheric plasma-synthesized polyethylene glycol-functionalized gold nanoparticles. Nanomaterials. 2021;11(7):1678. https://doi.org/10.3390/nano11071678

4. Bisht S. Plasma applications for environmental protection. Int J Eng Adv Technol. 2014;3(5):77–81. https://doi.org/28d6a8f084e88872c1207bc97

5. Saleh KM. Study influence of substrate temperature on optical properties of CdS thin films prepared by chemical spray pyrolysis. Ibn Al-Haitham J Pure Appl Sci. 2019;32(1):7–16. https://doi.org/10.30526/32.1.1982

6. Bedolla-Hernández M. Electrodeposition mechanism of chromium nanoparticle coatings: modeling and experimental validation. Chem Eng Sci. 2022;252:117291. https://doi.org/10.1016/j.ces.2021.117291

7. Folkenant M. Structure and properties of Cr–C/Ag films deposited by magnetron sputtering. Surf Coat Technol. 2015;281:184–192. https://doi.org/10.1016/j.surfcoat.2015.09.054

8. Zhu X. Spin glass state in chemical vapor-deposited crystalline Cr2Se3 nanosheets. Chem Mater. 2021;33(10):3851–3858. https://doi.org/10.1021/acs.chemmater.1c01222

9. Azeez NA. Nano-remediation of toxic heavy metal contamination: Hexavalent chromium [Cr (VI)]. Chemosphere. 2021;266:129204. https://doi.org/10.1016/j.2020.129204

10. Mahmoud ME. Recent advances in adsorptive removal and catalytic reduction of hexavalent chromium by metal–organic frameworks composites. J Mol Liq. 2022;347:118274. https://doi.org/10.1016/j.molliq.2021.118274

11. Kolay A. Selenium nanoparticle-decorated silicon nanowires with enhanced liquid-junction photoelectrochemical solar cell performance. J Phys Chem C. 2019;123(14):8614–8622. https://doi.org/10.1021/acs.jpcc.9b00062

12. Kanagaraj J. Biosorption of trivalent chromium from wastewater: an approach towards green chemistry. Chem Eng Technol. 2014;37(10):1741–1750. https://doi.org/10.1002/ceat.201200716

13. Zhang B. Selenium (Ⅳ) alleviates chromium (Ⅵ)-induced toxicity in the green alga Chlamydomonas reinhardtii. Environ Pollut. 2021;272:116407. https://doi.org/10.1016/j.envpol.2020.116407

14. Khatami M, Alijani HQ, Sharifi I. Biosynthesis of bimetallic and core-shell nanoparticles: their biomedical applications–a review. IET Nanobiotechnol. 2018;12(7):879–887. https://doi.org/10.1049/iet-nbt.2017.0308

15. Gawande MB. Core-shell nanoparticles: synthesis and applications in catalysis and electrocatalysis. Chem Soc Rev. 2015;44(21):7540–7590. https://doi.org/10.1039/C5CS00343A

16. Parauha YR, Sahu VD. Prospective of combustion method for preparation of nanomaterials: A challenge. Mater Sci Eng B. 2021;267:115054. https://doi.org/10.1016/j.mseb.2021.115054

17. Rajput N. Methods of preparation of nanoparticles—a review. Int J Adv Eng Technol. 2015;7(6):1806. file:///C:/Users/hp/Downloads/Nano3%20(3).pdf

18. Hrdlicka M. Optical parameters of In–Se and In–Se–Te thin amorphous films prepared by pulsed laser deposition. J Phys Chem Solids. 2007;68(5–6):846–849. https://doi.org/10.1016/j.jpcs.2007.02.043

19. Afzal A. Structural and magnetic phase transition of sol–gel-synthesized Cr2O3 and MnCr2O4 nanoparticles. J Sol-Gel Sci Technol. 2016;80:96–102. https://doi.org/10.1007/s10971-016-4066-4

20. Rappaport WD. Effect of electrocautery on wound healing in midline laparotomy incisions. Am J Surg. 1990;160(6):618–20. https://doi.org/10.1016/s002-9610(05)80757-3

21. Maguire P. Continuous in-flight synthesis for on-demand delivery of ligand-free colloidal gold nanoparticles. Nano Lett. 2017;17(3):1336–1343. https://doi.org/10.1021/acs.nanolett.6b03440

22. Palaskar S. Dielectric barrier discharge plasma induced surface modification of polyester/cotton blended fabrics to impart water repellency using HMDSO. J Appl Polym Sci. 2011;122(2):1092–100. https://doi.org/10.1002/app.34237

23. De Geyter N. Effect of electrode geometry on the uniformity of plasma-polymerized methyl methacrylate coatings. Prog Org Coat. 2011;70(4):293–299. https://doi.org/10.1016/j.porgcoat.2010.11.009

24. Al-Halbosiy M. Effect gold nanoparticles generated by cold plasma for mineral blood. AIP Conf Proc. 2020; https://doi.org/10.1063/5.0032718

25. Patil PS. Versatility of chemical spray pyrolysis technique. Mater Chem Phys. 1999;59(3):185–98. https://doi.org/10.1016/S0254-0584(99)00049-8

26. Mohammed MS. Plasma jet prepared gold and silver nanoparticles to induce caspase-independent apoptosis in digestive system cancers. Mater Sci Forum. 2022; https://doi.org/10.4028/www.scientific.net/MSF.1050.51

27. Khalaji D. Structural, Optical and Magnetic Studies of Cr2O3 Nanoparticles Prepared by Microwave-Assisted. Nanochem Res. 2021;6(1):18–24. https://doi.org/10.22036/NCR.2021.01.003

28. Jiang FW, Cai G. Facile synthesis and optical properties of small selenium nanocrystals and nanorods. Nanoscale Res Lett. 2017;12:1–6. https://doi.org/10.1186/s11671-017-2165-y

29. Abdul-Ameer ZN. Novel Co-Precipitation method for synthesis of nanostructured nickel oxide in accordance to pH: Structural and optical properties as an active optical filter. Ibn Al-Haitham J Pure Appl Sci. 2019;32(1):1–6. https://doi.org/10.30526/32.1.1974

30. El-Nahas S. Controlled morphological and physical properties of ZnO nanostructures synthesized by domestic microwave route. Mater Chem Phys. 2021;258:123885. https://doi.org/10.1016/j.matchemphys.2020.123885

31. Dawood M. Effect of Li doping on structure and optical properties of NiO nano thin-films by SPT. AIP Conf Proc. 2020; https://doi.org/10.1063/5.0000136

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Published

20-Jul-2025

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Section

Physics

How to Cite

[1]
Hilmi, T.A. and Al-Ansari, R.A. 2025. Impacts of Non-Thermal Plasma on the Structural and Optical Characteristics of Cr:Se Core-Shell Thin Films Synthesized Using Chemical Spray Pyrolysis. Ibn AL-Haitham Journal For Pure and Applied Sciences. 38, 3 (Jul. 2025), 137–146. DOI:https://doi.org/10.30526/38.3.4026.