Study on The Efficiency of Zinc Oxide Solid-State Solar Cells Using Organic Dyes Based on Indolene D102 Dye
DOI:
https://doi.org/10.30526/38.3.4095Keywords:
Efficiency, Indoline D102 Dye, Zinc Oxide, Solid-State Solar CellsAbstract
In this work, two carrier concentrations with dye D102 were used in a dye-sensitized solar cell to perform a comparative evaluation of the efficiency and influence on the study of key parameters affecting the device performance. To achieve this goal, the cell transfer power, current, current density and fill factor were calculated to estimate the power conversion efficiency (PCE) of DSSCs. Electrons move from the excited state of indolene D02 to the conduction band of ZnO to produce current for DSSCs through the assumed energy levels of donor indolene and acceptor ZnO in the hetero junction device to be continuous. The effect of carrier concentration and coupling strength on the improvement of the contact efficiency of D102 hetero junction dye with ZnO-based DSSCs is discussed using quantum charge transfer theory. D102-ZnO with ethanol-based DSSCs with PCEs up to (14.368%) were developed and the main J-V properties were investigated, the corresponding carrier concentration efficiency of )1/m3) is much lower (7.256%) compared to using a concentration of )1/m3) to reach (14.368%), mainly due to the lower charge transport.
References
1. Majeed Y, Khan MU, Waseem M, Zahid U, Mahmood F, Majeed F, et al. Renewable energy as an alternative source for energy management in agriculture. Energy Reports. 2023;10:344–59. https://linkinghub.elsevier.com/retrieve/pii/S2352484723010521
2. Hmouda AMO, Orzes G, Sauer PC. Sustainable supply chain management in energy production: A literature review. Renew Sustain Energy Rev. 2024;191:114085. https://linkinghub.elsevier.com/retrieve/pii/S1364032123009437
3. Nahi Abd Ali N, Hadi J.M.Al-Agealy, Hossain Milani Moghaddam. Theoretical Calculation of The Fill Factor of N749/〖TiO〗_2 Solar Cells. Ibn AL-Haitham J Pure Appl Sci. 2023;36(4):147–58.
4. Barasa Kabeyi MJ, Akanni. Olanrewaju O. Solar Energy as a Sustainable Energy for Power Generation. 2024;1008–22.
5. Maka AOM, Alabid JM. Solar energy technology and its roles in sustainable development. Clean Energy. 2022 Jun 1;6(3):476–83. https://academic.oup.com/ce/article/6/3/476/6606003
6. Faheem F, Arsalan M, Khan ME. Recent developments of nanocomposites in energy-related applications. In: Nanocomposites-Advanced Materials for Energy and Environmental Aspects. Elsevier; 2023. p. 111–27. https://linkinghub.elsevier.com/retrieve/pii/B9780323997041000230
7. Al-Agealy HJM, Hassooni MA, Ghadhban RQ, Obaid MA, Saud AJ. Theoretical calculation of electronic rate at cis-bisisothiocyanatobis (2,2′-bipyridyl-4,4′-dicarboxylato) ruthenium(II) N3 dye contact to GaAs semiconductor. In 2023. p. 070012. http://aip.scitation.org/doi/abs/10.1063/5.0157254
8. Al Maadhede TS, Jumali MH, Al-Agealy HJ, Yap CC, Al-Douri Y. Improved performance of D149 dye-sensitized ZnO-based solar cell under solvents activation effect. Eur Phys J Plus [Internet]. 2023 Apr 10;138(4):325. https://link.springer.com/10.1140/epjp/s13360-023-03935-0
9. Maadhede TS Al, Jumali MH, Al-Agealy HJM, Yap CC, Ayada AD, Shaban AH. Effect of solvents on performance of Alq3/ZnO solar cells: A theoretical approach. Energy Reports. 2023 Sep;9:427–34. https://linkinghub.elsevier.com/retrieve/pii/S2352484723009897
10. Ali NNA, Al-Agealy HJM. A theoretical model for efficiency N749 black dye-sensitized solar cell based on TiO2 photoanode. In 2023. p. 020019. https://aip.scitation.org/doi/abs/10.1063/5.0172672
11. Al-Agealy HJM, Al Maadhede TS, Jumali MH, Yap CC. A Theoretical Study of The Influence of Donor Sensitize Dye on Performance of Dye-sensitized Solar Sells DSSCs. Ibn AL-Haitham J Pure Appl Sci. 2023;36(4):171–81.
12. Balapure A, Ray Dutta J, Ganesan R. Recent advances in semiconductor heterojunctions: a detailed review of the fundamentals of photocatalysis, charge transfer mechanism and materials. RSC Appl Interfaces. 2024;1(1):43–69.
13. Min KH, Min KH, Kim T, Kang MG, Song HE, Kang Y, et al. An analysis of fill factor loss depending on the temperature for the industrial silicon solar cells. Energies. 2020;13(11):1–10.
14. Shnain FA, Al-Agealy HJM. A theoretical calculation of the efficiency of indoline dyes-sensitized contact with ZnO in solar cell. J Theor Appl Phys. 2024. https://oiccpress.com/journal-of-theoretical-and-applied-physics/article/a-theoretical-calculation-of-the-efficiency-of-indoline-dyes-sensitized-contact-with-zno-in-solar-cell/
15. Gezgin M, Arslan BS, Avcı D, Nebioğlu M, Şişman İ. Novel D–π–A dye as a co-sensitizer of indoline and benzothiadiazole dyes to enhance photovoltaic performance of dye-sensitized solar cells. J Photochem Photobiol A Chem. 2025;458:115977.
16. Kim JY, Kim YH, Kim YS. Indoline dyes with various acceptors for dye-sensitized solar cells. Curr Appl Phys. 2011;11(1 SUPPL.):S117–21. https://dx.doi.org/10.1016/j.cap.2010.11.098
17. Xu J, Zhang H, Liang G, Wang L, Xu W, Cui W, et al. DFT Studies on the electronic structures of indoline dyes for dye-sensitized solar cells. J Serbian Chem Soc. 2010;75(2):259–69.
18. Zhang D, Yu W, Zhang L, Hao X. Progress in the Synthesis and Application of Transparent Conducting Film of AZO (ZnO:Al). Materials (Basel). 2023;16(16).
19. Sasikumar R, Thirumalaisamy S, Kim B, Hwang B. Dye-sensitized solar cells: Insights and research divergence towards alternatives. Renew Sustain Energy Rev. 2024;199:114549.
20. Al-agealy HJM, Moghaddam HM. Theoretical Study of the Electronic Characteristic of a TiO 2 -N719 Dye - Sensitized Solar Cell. 2024;37(2):183–92.
21. Al Maadhde TS, Jumali MH, Al-Agealy HJM, Razak FBA, Yap CC. An investigation of the fill factor and efficiency of molecular semiconductor solar cells. Mater Sci Forum. 2021;1039 MSF(August):373–81.
22. Al-Obaidi SS, Al-Agealy HJM, Abbas SR. Theoretical Evaluation of Flow Electronic Rate at Au/TFB Interface. J Phys Conf Ser. 2021;1879(3).
23. H.J.M.Al-Agealy, M.A.Hassooni. A Theoretical Study of the Effect of The Solvent Type on The Reorganization Energies of Dye - Semiconductor System Interface. Ibn Al- Haitham J Pure Appl Sci. 2010;2010(3).
24. Jayachithra J V, Elampari K, Meena M. Fabrication of TiO 2 based Dye-Sensitized Solar Cell using Nerium oleander as a sensitizer . IOP Conf Ser Mater Sci Eng. 2022;1263(1):012018.
25. Farzadi R, Milani Moghaddam H, Farmanzadeh D. Tuning the spin transport properties of ferrocene-based single molecule junctions by different linkers. Chem Phys Lett [Internet]. 2018;704:37–44. https://doi.org/10.1016/j.cplett.2018.05.037
26. Al-Agealy HJM, Haider Mahdi M, Hassooni MA, Younis TA. Study of the Effect of Concentration on the Efficiency of the Sensitive N749-TiO2Solar Cell. J Phys Conf Ser. 2024;2754(1).
27. Al-Agealy HJM, Moghaddam HM, Ali MJ. Theoretical Study of the Electronic Characteristic of a TiO2-N719 Dye-Sensitized Solar Cell. Ibn AL-Haitham J Pure Appl Sci. 2024;37(2):183–92.
28. Ali MJ, Al-Agealy HJM, Moghaddam HM. Theoretical calculations of the efficiency of a TiO2-N719 dye-sensitizer solar cell (DSSC) using charge transfer theory. In: AIP Conference Proceedings. AIP Publishing; 2024.
29. Krüger J, Plass R, Grätzel M, Matthieu HJ. Improvement of the photovoltaic performance of solid-state dye-sensitized device by silver complexation of the sensitizer cis-bis (4, 4′-dicarboxy-2, 2′ bipyridine)-bis (isothiocyanato) ruthenium (II). Appl Phys Lett. 2002;81(2):367–9.
30. Mohsin MAR, Al-Agealy HJM. Theoretical investigation of charge transfer at N3 sensitized molecule dye contact with TiO2 and ZnO semiconductor. In: AIP Conference Proceedings. AIP Publishing; 2022.
31. Haynes WM. CRC handbook of chemistry and physics. CRC press; 2016.
32. Sabri NA, Al-Agealy HJM. Theoretical studies of electronic transition characteristics of senstizer molecule dye N3-SnO2 semiconductor interface. In: AIP Conference Proceedings. AIP Publishing; 2022.
33. Park J, Rim YS, Senanayake P, Wu J, Streit D. Electrical defect state distribution in single crystal ZnO schottky barrier diodes. Coatings. 2020;10(3).
34. Prajapat K, Dhonde M, Sahu K, Bhojane P, Murty VVS, Shirage PM. The evolution of organic materials for efficient dye-sensitized solar cells. J Photochem Photobiol C Photochem Rev. 2023;55:100586.
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