Synthesis and Spectroscopic of Some new Metal Ions Complexes's with [N-(4-Methoxy Benzoyl Amino)-Thioxo Methyl] Leucine

Authors

  • Basima M. Sarhan
  • Hassan A. Hassan
  • Bushra M. Fayyadh

Keywords:

4-Methoxy benzoyl isothiocyanate, leucine, complexes.

Abstract

 A new ligand [N-(4-methoxy benzoyl amino)-thioxo methyl ] leucine  (MBL) was prepared from the reaction of (4-methoxy benzoyl isothiocyanate with leucine acid in molar ratio (l:l), it was characterized by elemental analysis (C.H.N.S), FT-IR, UV-Vis, 1H and 13CNMR. The complexes of the bivalent ions (Mn, Fe, Co, Ni, Cu, Zn, Cd and Hg ) have been prepared and characterized too.       The structural was established by elemental analysis (C.H.N.S), FT-IR, UV-Vis spectra,  conductivity measurements atomic absorption and magnetic susceptibility and determination of molar ration (M:L). The complexes showed characteristic behavior of tetrahedral geometry around the metal ions except with (Cu) complex showed square planer.

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Published

24-Apr-2017

Issue

Section

Chemistry

How to Cite

[1]
Sarhan, B. M. et al. 2017. Synthesis and Spectroscopic of Some new Metal Ions Complexes’s with [N-(4-Methoxy Benzoyl Amino)-Thioxo Methyl] Leucine. Ibn AL-Haitham Journal For Pure and Applied Sciences. 26, 3 (Apr. 2017), 313–323.